High Resolution Spectra Of Some Silicon Compounds

S. E. Rodgers; V. F. Kalasinsky

doi:10.1117/12.932194

29 October 1981 High Resolution Spectra Of Some Silicon Compounds

S. E. Rodgers, V. F. Kalasinsky

Proceedings Volume 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy; (1981) https://doi.org/10.1117/12.932194
Event: 1981 International Conference on Fourier Transform Infrared Spectroscopy, 1981, Columbia, United States

Abstract

The infrared spectra of gaseous vinylsilane, cyclopropylsilane, vinyltrichlorosilane, cyclopropyltrichlorosilane, and silacyclopentane have been recorded. Barriers to internal rotation have been calculated for vinylsilane and cyclopropylsilane from an analysis of combination and difference bands associated with the Si-H stretches. Vibrational assignments have been made for vinyltrichlorosilane and cyclopropylsilane. High resolution spectra of the combination and difference bands involving the Si-H stretches and the ring-puckering vibration in silacyclopentane have been analyzed, and the new assignment is found to be completely consistent with existing low-frequency data. The structural implications of the results are discussed.

Citation Download Citation

S. E. Rodgers and V. F. Kalasinsky "High Resolution Spectra Of Some Silicon Compounds", Proc. SPIE 0289, 1981 Intl Conf on Fourier Transform Infrared Spectroscopy, (29 October 1981); https://doi.org/10.1117/12.932194

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