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An Immersion grating is a powerful optical device for the infrared high-resolution spectroscope. We already fabricated the large CdZnTe(CZT) immersion grating (Sukegawa et al. (2012), Fig.1)[1][2][3] and Germanium(Ge) immersion grating (Sukegawa et al. (2015), Fig.2)[4]. Ge is the best material for a mid-infrared immersion grating because of Ge has very large reflective index (n=4.0).
Takashi Sukegawa,Yukinobu Okura, andTomonao Nakayasu
"Development of INP immersion grating for the near- to mid-infrared wavelength", Proc. SPIE 10562, International Conference on Space Optics — ICSO 2016, 1056206 (25 September 2017); https://doi.org/10.1117/12.2296077
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Takashi Sukegawa, Yukinobu Okura, Tomonao Nakayasu, "Development of INP immersion grating for the near- to mid-infrared wavelength," Proc. SPIE 10562, International Conference on Space Optics — ICSO 2016, 1056206 (25 September 2017); https://doi.org/10.1117/12.2296077