We have studied the dependence of solar cell performance characteristics on diffusion temperature and time, for cells made by the closed-ampoule thermal diffusion of S into Cd-doped InP substrates of starting doping 1.7x 1016 cm-3. Diffusions were performed at 600, 625, 650, 700, and 725°C for 3 hours, 675°C for 1, 2, 3 and 4 hours, and, on specially treated substrates with phosphorus-rich surfaces, at 650 and 660°C for 3 hours. We have measured Isc, Voc, FF, η, spectral response, J0 and A factor, series and shunt resistances, and emitter sheet resistance and specific contact resistance of front metallization. Our results indicate that for best solar cell efficiency, the diffusion temperature should be between 650 and 675°C and the diffusion time should be from 1 to 3 hours, for our Cd-doped material.
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