We have developed and characterized large volume amorphous (a-) selenium (Se) stabilized alloys for room temperature
medical imaging devices and high-energy physics detectors. The synthesis and preparation of well-defined and high
quality a-Se (B, As, Cl) alloy materials have been conducted using a specially designed alloying reactor at EIC and
installed in an argon atmosphere glove box. The alloy composition has been precisely controlled and optimized to ensure
good device performance. The synthesis of large volume boron (B) doped (natural and isotopic 10B) a-Se (As, Cl) alloys
has been carried out by thoroughly mixing vacuum distilled and zone-refined (ZR) Se with previously synthesized Se-As
master alloys, Se-Cl master alloys and B. The synthesized a-Se (B, As, Cl) alloys have been characterized by x-ray
diffraction (XRD), differential scanning calorimetry (DSC), Fourier transform infra-red spectroscopy (FTIR), x-ray
photoelectron spectroscopy (XPS), inductively coupled plasma mass spectroscopy (ICP-MS), and detector testing. The a-
Se alloys have shown high promise for x-ray detectors with its high dark resistivity (1010-1013 Ωcm), good charge
transport properties, and cost-effective large area scalability. Details of various steps about detector fabrication and
testing of these imaging devices are also presented.
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