Thermal radiation from high-temperature application conditions of infrared windows can cause serious interference with infrared imaging. To suppress the thermal radiation from the window, the modulation effects of the optical properties and curvature characteristics of the two surfaces on the thermal radiation distribution from the window are investigated, respectively. The film–substrate–film radiation system is modeled. And the backward emissivity in the different cases of surface optical properties is investigated by the application of zinc sulfide (ZnS) windows and Y2O3 thin films as an example. It is shown that the backward emissivity is suppressed when the outer surface reflectivity is lower and the inner surface reflectivity is higher. A new definition of spectral directional locational emissivity is proposed to characterize the nonplate window emissivity. A model of thermal radiation propagation from the spherical substrate is developed. The emissivity distribution of the window with different curvature characteristics is investigated. It is shown that the curvature radius of the two surfaces can be matched to change the spatial distribution of the emissivity to reduce the effect of thermal radiation on the imaging of the backward optical system.