Dr. Hameed A. Al Attar Profile

Dr. Hameed A. Al Attar

Research Associate at Univ of Durham

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Proceedings Article | 29 July 2005 Paper

White polymeric light-emitting diode based on a fluorene polymer/Ir complex blend system

Hameed Al Attar, Andy Monkman, Mustafa Tavasli, Sylvia Bettington, Martin Bryce

Proceedings Volume 5961, 596108 (2005) https://doi.org/10.1117/12.629482

KEYWORDS: Polymers, Organic light emitting diodes, External quantum efficiency, Electroluminescence, Absorption, Iridium, Light emitting diodes, Aluminum, Doping, Complex systems

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New extended fluorenylpyridine ligands FlnPy (n=1,3,5) and their triscyclometalated iridium (III) complexes Ir[FlnPy]₃ 3, 4, and 5 have been synthesised and their photophysical properties have been studied. The lowest energy (emissive) excited state of the complexes 3-5 is dominated by ligand centered ³(π→π*) triplet states, as observed in their ligands. Efficient white-polymeric light-emitting diodes (PLED) were fabricated as a single active layer containing blue emitting poly (9,9-bis(2-ethylhexyl)fluorine-2,7- diyl) endcapped with bis(4-methylphenyl)phenylamine (PF2/6am4), and yellow-orange emitting from Iridium complex 4. The fluorene-like ligands in the blended device prevent phase segregation and also enhance energy transfer from the polymer host to the guest due to efficient overlap of wavefunction (Dexter process) and host singlet emission and guest absorption bands (F&diaero;rster process) which reduces the loading level required to produce white emission. The two emitted colours complement each other and doping levels between 2% to 3% produce white emission. Above a certain current density depending on the doping level the device CIE coordinates become bias independent and a stabilised white emission can be obtained. A white emission PLED (coordinate (0. 348, 0.367) of peak external quantum efficiency (EQE) of 2.8 %, and luminance of 16000 cd/m2) at applied voltage of 5V (ie. 4.57 cd/A) was obtained. device CIE coordinates become bias independent and a stabilised white emission can be obtained. A white emission PLED (coordinate (0. 3477, 0.3667) of peak external quantum efficiency (EQE) of 2.8 %, and luminance of 16000 cd/m2 at applied voltage of 5V (ie. 4.57 cd/A) was obtained.

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