It is possible to tailor the band gap of the strain-balanced quantum well solar cell to match the local solar spectral
conditions by altering the quantum well depth. This has led to a recent single-junction world-record efficiency of 28.3%,
as well as giving advantages for current matching in multi-junction solar cells. Radiative recombination is the dominant
loss mechanism for the strain-balanced quantum well solar cell, so practical improvements focus on techniques for light
management in the cell, such as enhancing the optical path length with epitaxial mirrors. Furthermore, the compressive
strain in the quantum wells suppresses emission into TM-propagating modes, reducing the overall optical loss and
increasing the cell efficiency. As biaxial strain can only be engineered into a cell on the nanoscale, quantum well solar
cells are seen to have a fundamental efficiency advantage over bulk semiconductor cells.
We demonstrate how GaAs/AlGaAs regrowth upon patterned InGaP can be utilised to realise self-aligned lasers, window
structured superluminescent diodes and distributed feedback lasers. Such realisation demonstrates the promise of this
methodology for GaAs-based opto-electronic integrated circuits through new capability for buried waveguides, low
reflectivity facets and gratings structures.
We report the realisation of spectroscopic broadband transmission experiments on quantum cascade lasers (QCLs)
under continuous wave operating conditions for drive currents up to laser threshold. This technique allows, for the first
time, spectroscopic study of light transmission through the waveguide of QCLs in a very broad spectral range (λ~1.5-12
μm), limited only by the detector response and by interband absorption in the materials used in the QCL cladding
regions. Waveguide transmittance spectra have been studied for both TE and TM polarization, for InGaAs/InAlAs/InP
QCLs with different active region designs emitting at 7.4 and 10μm. The transmission measurements clearly show the
depopulation of the lower laser levels as bias is increased, the onset and growth of optical amplification at the energy
corresponding to the laser transitions as current is increased towards threshold, and the thermal filling of the second
laser level and decrease of material gain at high temperatures. This technique also allows direct determination of key
parameters such as the exact temperature of the laser core region under operating conditions, as well as the modal gain
and waveguide loss coefficients.
In this paper we present single mode quantum cascade lasers (QCLs) based on the GaAs and the InP material systems. We show results for first- and second-order distributed feedback (DFB) QC lasers with surface gratings. The InP based lasers are grown by metalorganic vapor phase epitaxy (MOVPE) and show single mode continuous wave emission up to 200 K. In pulsed operation we achieved single mode surface emission peak output powers exceeding 1 Watt at room temperature. The presented GaAs/AlGaAs laser features an air/AlGaAs waveguide, combined with a second-order distributed feedback grating. That laser shows 3 Watts of single mode output power via the surface at 78 K.
The operation of the Hot Electron Light Emitting and Lasing in Semiconductor Heterostructure -- Vertical Cavity Surface Emitting Laser (HELLISH-VCSEL) devices is based on hot carrier transport parallel to the layers of Ga1-xAlxAs p-n junction. It is therefore a field - effect device and the light emission from the device is independent of the polarity of the applied voltage. In this study, we present the temperature dependence of the operational characteristics of the device. Experimental studies comprising of the measurements of the I-V characteristics, electroluminescence, reflectivity, and temperature dependent light-applied electric field (L-F) characteristics are conducted to find the optimum operating temperature of the device.
We report MOVPE-grown quantum cascade lasers with operating wavelengths between λ~7.5-9.5μm with threshold current densities as low as 2.4kA/cm2 at room temperature. Seven wafers grown for operation at ~9μm show a variation of just 3% in the superlattice periods obtained from X-ray analysis, and laser emission is observed from all wafers with a ~5meV spread of emission energies. Multimode Fabry-Perot and singlemode distributed feedback lasers have been fabricated, operating at λ~7.8μm at room temperature, corresponding with absorption lines in the infrared spectra of methane. In addition, we have produced a strain compensated MOVPE-grown quantum cascade laser operating at λ~4.5μm.
We demonstrate the optical manipulation of microscopic particles within a single optoelectronic device, whose footprint measures 2mm by 3mm, and which is realised entirely in planar technology. The device is fabricated in a GaAs/AlGaAs heterostructure, and consists of two facing banks of lasers that are separated by an etched channel. Particles within this channel experience the simple trapping force of two counter-propagating beams. The lasers operate at a wavelength of 980nm, and each gives up to 10mW of power in a single transverse optical mode. This power is sufficient to deflect, decelerate and hold a variety of micron-scale particles, including fluorescent polymer spheres, and cells in solution. The first results were obtained using planar etched facets, giving highly divergent beams. More elegant beam shapes can be produced by etching curved facets.
The main attractions of this technology are its size and self-alignment properties: Many devices can fit into a fraction of the space occupied by a traditional tweezer set-up. Using photo-lithography, the alignment of the lasers is 'perfect', avoiding the difficulties experienced in traditional tweezers. The concept we demonstrate is a truly integrated optical tweezer that is mass-producible and does not require any complex instrumentation to operate.
In semiconductor microcavities (MCs) with embedded quantum wells (QW) a strong two-dimensional (2D) confinement of the light in the growth direction leads to an enhanced exciton-photon interaction, which results in the formation of mixed exciton-photon states described in terms of quasi 2D-polaritons. The density of these states is strongly reduced compared to exciton one, due to a very small in-plane mass. As a result, one can hope that the high filling of the polariton states near the polariton band bottom can be achieved at relatively small total density without destroying the strong coupling regime. However such a filling never was reached at low excitation density range where the polariton relaxation to the polariton branch bottom is determined by the emission of acoustic phonons. The reason is in the fact that the polariton lifetime is comparable with phonon scattering time. As a result, the energy distribution of polaritons clearly demonstrates 'bottleneck effect' both under the above band gap excitation and the resonant excitation below free exciton level. However the high occupation of polariton states near the band bottom is relatively easy reached under conditions of a strong resonant excitation into the lower polariton (LP) branch at particular wavenumbers close to the inflection point of the LP dispersion. It is explained as the result of stimulated hyper-Raman scattering (or four-wave mixing) of pumped polaritons with (Ep, kp) to states with the energy and momentum [E1, k1 approximately 0] and [E2 = 2Ep - E1, k2 = 2kp], which referred to as the 'signal' and 'idler,' respectively. Here we investigate the influence of a temperature and an additional above band gap excitation on the stimulated scattering in MCs. A GaAs/AlAs MC containing 6 InGaAs quantum wells in the active layer (Rabi splitting Ω of 6 - 7 meV) has been investigated in a wide range of detunings between free exciton level and bottom of the photonic mode from δ = 0 to -3 meV. The resonance excitation into an LP branch was carried out with a tunable Ti-sapphire laser. The HeNe laser was used for the additional above GaAs band gap excitation. The sample was mounted in a helium thermostat with the temperature control at T = 5 - 30 K.
Theoretical and experimental results concerning the study of a novel wavelength converter amplifier, which can be tuned, with the amplification of an external voltage are presented. The device consists of a Ga1-xAlxAs graded quantum well, placed on the n-side of the depletion region of a Ga1-xAlxAs p-n junction. As a result of the competition between the built-in field and the grading, in the absence of an external bias, the quantum well acts as an isolated well. Forward biasing of the junction reduces the built-in field; thus the field associated with the grading becomes effective. The tuning of the operation wavelength is based on the anti-Quantum Confined Stark Effect and achieved during the forward biasing. In this study we present the numerical results based on a 2D modeling of the device where exciton binding energy, absorption co-efficient and transition energy are obtained as a function of applied field. Experimental results show a tuning range of around 40nm.
MOVPE grown InAlGaAs SQW lasers for approximately 730 nm have been optimized for low oxygen incorporation, where diethylether associated with trimethylindium (TMI) provides the dominant oxygen impurity. An ether free preparative route to TMI, together with a large indium fraction for the SQW has provided device lifetimes of approximately 2000 hours when operating at 1.2 W and 743 nm.
The hot Electron Light Emission and Lasing in Semiconductor Heterostructures devices (HELLISH-1) is novel surface emitter consisting of a GaAs quantum well, within the depletion region, on the n side of Ga1-xAlxAs p- n junction. It utilizes hot electron transport parallel to the layers and injection of hot electron hole pairs into the quantum well through a combination of mechanisms including tunnelling, thermionic emission and diffusion of `lucky' carriers. Super Radiant HELLISH-1 is an advanced structure incorporating a lower distributed Bragg reflector (DBR). Combined with the finite reflectivity of the upper semiconductor-air interface reflectivity it defines a quasi- resonant cavity enabling emission output from the top surface with a higher spectral purity. The output power has increased by two orders of magnitude and reduced the full width at half maximum (FWHM) to 20 nm. An upper DBR added to the structure defines HELLISH-VCSEL which is currently the first operational hot electron surface emitting laser and lases at room temperature with a 1.5 nm FWHM. In this work we demonstrate and compare the operation of UB-HELLISH-1 and HELLISH-VCSEL using experimental and theoretical reflectivity spectra over an extensive temperature range.
Spontaneous emission control has been achieved in GaAs/AlGaAs quantum well lasers by the use of Distributed Bragg microcavity perpendicular to the quantum wells. The room temperature emission is inhibited whilst below 130 K there is an enhancement. These changes to the spontaneous emission process directly effect the threshold current producing a 25% reduction at room temperature. Theoretical modeling of the lasers is in agreement with the experimental results and highlights the effect of the microcavity on the field-dipole interaction.
AlxGayIn1-x-yAs/AlGaAs quantum well lasers offer the prospect of devices at intermediate wavelengths between about 690 nm and 750 nm with applications in areas such as photodynamic therapy. The larger thermal conductivity of AlGaAs compared to that of AlGaInP could make the AlxGayIn1-x-yAs system attractive for high power devices. The incorporation of indium in the quantum well also improves material quality and introduces compressive strain which enhances the intrinsic performance beyond that of the phosphide system due to the larger spin orbit splitting and more similar electron and hole density of states in AlxGayIn1-x-yAs compared with GaxIn1-xP. We have modeled the gain and radiative recombination of AlxGayIn1-x-yAs wells with Al0.45Ga0.55As barriers at a wavelength in the region 720 to 730 nm. This shows that the intrinsic gain-current characteristic is superior to that of an idealized GaInP/AlGaInP laser at the same wavelength. Devices have been fabricated, which operate at 685 nm and 750 nm at room temperature, and the length dependence of the threshold current, measured as a function of temperature between 140 K and 400 K, analyzed. At the shorter wavelength the room temperature threshold current is dominated by thermally activated carrier loss from the well. Although this could be reduced by further optimization, short wavelength operation is severely restricted by the band gap of the AlGaAs barriers and this material system will be of greatest benefit for devices at wavelengths greater than about 710 nm.
Despite their complexity, vertical cavity surface emitting lasers (VCSELs) have become key devices for future low cost optical interconnections. The high quality dielectric distributed Bragg reflectors (DBRs) mirrors possible in the AlGaAs system have made GaAs based devices the most successful and most studied VCSELs. This paper reviews the work carried out at the University of Sheffield on devices which employ AlGaAs mirrors and emit at wavelengths across the range 640 to 1100 nm. The active layers in the different designs contain variously quantum wells of InGaAs, GaAs, AlGaAs, and AlGaInP. A major limitation of using Al based compounds, particularly AlGaAs, at shorter wavelengths has previously been the presence of oxygen and other impurities. But by improving the crystal quality and purity, respectable performance of arsenide compounds has been extended to the sub 700 nm wavelength region and further improvements are expected through structural optimization and the application of strained AlInGaAs layers. Issues regarding the growth, device resistance and reproducibility of emission wavelength are also discussed.
Vertical cavity surface emitting lasers (VCSELs) have been the subject of intense research in recent years. The compact nature of the devices means that heat generated within is not as readily dissipated as with more conventional stripe geometry lasers. Advances in the design of distributed Bragg reflector (DBR) cavity mirrors and intracavity contact schemes have reduced the threshold voltage from greater than 10 V to little more than the lasing photon potential, in some cases. However, thermal management is still a limiting factor for high power or high efficiency output from VCSELs By analyzing a variety of devices we have devised a simple but powerful model to explain the current-light response of VCSELs which is strongly dependant on the temperature rise in the active layer. Effects of the relative position of the cavity resonance and gain spectrum are also discussed.
Tuning of the vacuum Rabi exciton-photon coupling in semiconductor quantum microcavity structures by external electric and magnetic fields is presented. Contrasting effects due to the two external perturbations are found, principally due to the decrease of exciton oscillator strength in electric field and increase of oscillator strength in magnetic field. The strong coupling limit is easily achieved in these high quality structures with line widths on resonance as small as 1 meV. In addition to the tuning phenomena, the effects of exciton Zeeman splitting on the spectra and unexpected linewidth narrowing phenomena on resonance are reported.
Micro-resonator modulators exploiting the quantum confined Stark shift and incorporating the asymmetric Fabry-Perot have been fabricated which exhibit high contrast (15 - 20 dB), and large reflectivity changes (> 50%) at low voltages (3V - 4V). This paper will review progress made in the development of these devices and will consider how the performance can be modified, post growth, by use of intermixing techniques to modify the shape of the quantum wells. The asymmetric Fabry Perot structure is also a convenient configuration to investigate the intermixing process itself. Measurement of the lateral extent of the intermixing process promoted by vacancies in GaAs/AlGaAs structures obtained using this structure are reported.
Studies have been made of the effect of boron and fluorine impurity induced disordering on the refractive index of AlxGaixAs multiple quantum well waveguides. A grating coupler formed in low-index material was used to determine experimentally the changes in refractive index obtained in partially disordered material. Over the measured wavelength range 820-920 nm substantial changes 1 in the refractive index were observed. Fluorine was found to produce larger changes than boron for similar annealing conditions.
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