Metallic nanorod metamaterials, arrays of vertically aligned nanorods embedded in an alumina matrix (diameter ~80 nm, length 100-250 nm, period ~113 nm), have recently emerged as a flexible platform for applications in photonics, opto-electronics and sensing. The optical constants for these nanostructured materials are directly associated with their crystallinity. Controlling the crystallinity of these metamaterials in a fast manner has presented a new challenge. Here we show a laser annealing with a pulsed Nd:YAG laser (λ = 532 nm, FWHM 15 ns) to rapidly change the crystallinity of the metallic nanorods. The small column X-Ray diffraction characterization shows that not only the crystallinity of the metallic nanorods is changed, but also that evaporation of the metal occurs with laser annealing.
Hybrid nanostructures, comprising of a metal core and a semiconductor shell layer, shows great potential for a new generation of low-cost solar cells, due to their unique electronic and optical properties. However, experimental results have fallen far short of unltra-high efficiency (i.e. beyond Shockley-Queisser limit) predicted by theoretical simulation, limiting commercial application. Here, we experimentally design a non-transparent organic solar cell containing an array of Ag/ZnO nanowires, increasing internal quantum efficiency (IQE) by a factor of 2.5 compared with the planar counterpart, indicating a great enhancement of charge collection efficiency, due to the ultrafast Ag nanowire channels. Furthermore, we exploit this hybrid nanostructure as a perfect back reflector for semi-transparent solar cells, resulting in enhanced light absorption by a factor of 1.8 compared with the planar counterparts. The ability to enhance the charge collection and light absorption makes these Ag/ZnO nanostructures a flexible platform for the development of modern optoelectronic devices.
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