Paper
3 February 2017 Hydrogen donors in ZnO and TiO2
Eduard V. Lavrov
Author Affiliations +
Proceedings Volume 10036, Fourth Conference on Sensors, MEMS, and Electro-Optic Systems; 1003618 (2017) https://doi.org/10.1117/12.2245420
Event: Fourth Conference on Sensors, MEMS and Electro-Optic Systems, 2016, Skukuza, Kruger National Park, South Africa
Abstract
The results of combined IR absorption and photoconductivity studies on hydrogen donors in ZnO and TiO2 are presented. It is shown that hydrogen donors in ZnO and rutile TiO2 can be detected as Fano resonances in the photoconductivity spectra at the frequencies corresponding to the vibrational modes of these defects. In the case of anatase TiO2 IR absorption lines at 3412 and 3417 cm−1 are assigned to the stretching local vibrational modes of a donor in the neutral and the positive charge states, respectively. Interstitial hydrogen is suggested as a tentative model for the defect giving rise to these vibrational modes.
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Eduard V. Lavrov "Hydrogen donors in ZnO and TiO2", Proc. SPIE 10036, Fourth Conference on Sensors, MEMS, and Electro-Optic Systems, 1003618 (3 February 2017); https://doi.org/10.1117/12.2245420
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KEYWORDS
Hydrogen

Zinc oxide

Absorption

Infrared spectroscopy

Oxygen

Titanium dioxide

Crystals

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