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The Stark levels of the 4115/2 ground state manifold have been determined for Er3+-doped fluoride, fluorophosphate, and silicate bulk glasses from fluorescence-line-narrowing measurements at 4.2 K. Splittings between adjacent Stark levels were observed to be 20-80 cm-1. The total energy spread of the manifold ranged from 335 to 400 cm-1. The energy of a given Stark level varied up to 60 cm-1 depending on the particular Er3+ sites excited. Using the 4.2-K results, homogeneous broadening is found to be a reasonable approximation for the 300-K luminescence band.
S. Zemon,G. Lambert,W. J. Miniscalco,L. J. Andrews, andB. T. Hall
"Characterization Of Er3+-Doped Glasses By Fluorescence Line Narrowing", Proc. SPIE 1171, Fiber Laser Sources and Amplifiers, (15 February 1990); https://doi.org/10.1117/12.963155
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S. Zemon, G. Lambert, W. J. Miniscalco, L. J. Andrews, B. T. Hall, "Characterization Of Er3+-Doped Glasses By Fluorescence Line Narrowing," Proc. SPIE 1171, Fiber Laser Sources and Amplifiers, (15 February 1990); https://doi.org/10.1117/12.963155