The chiral effects displayed by trioxadecalin derived liquid crystals are summarized. All these mesogenic properties depend strongly on small changes in the molecular structure. It is therefore possible to obtain a wide array of different chiral effects like helix inversions, blue phases, TGBA phase, SC* phase to name only some of them by changing only a small part of the molecule, meanwhile the basic mesogenic core is kept constant. In addition the mesogenic properties of new trioxadecalins are described, that have been obtained by a new synthetic pathway.
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