Labeling of pure vibrational states of water-like molecules

O. V. Naumenko; E. R. Polovtseva

doi:10.1117/12.820961

11 February 2009 Labeling of pure vibrational states of water-like molecules

O. V. Naumenko, E. R. Polovtseva

Proceedings Volume 7296, Fifteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics; 729602 (2009) https://doi.org/10.1117/12.820961
Event: Fifteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 2008, Krasnoyarsk, Russian Federation

Abstract

A problem of the consistent normal mode labeling for water-like molecules is discussed based on the effective vibrational Hamiltonian approach. The main contributions to the resulting vibrational wave functions of the H₂S molecule are presented. It is shown that due to resonance mixing, the proposed normal mode notations of the highly excited vibrational states of H₂S become ambiguous for the energies higher than 12000 cm^-1 and have to be used with caution.

Citation Download Citation

O. V. Naumenko and E. R. Polovtseva "Labeling of pure vibrational states of water-like molecules", Proc. SPIE 7296, Fifteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 729602 (11 February 2009); https://doi.org/10.1117/12.820961

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