Stress formation during the recording and bleaching of photopolymer holograms results in distortion of the internal diffractive structure and causes many undesirable effects. This is especially important in the case of holographic solar concentrators and similar holographic optical elements that are supposed to meet stringent specifications. We report a new digital holographic method to measure and study stress formation in photopolymers during hologram recording. A glass substrate, with one of its sides diffusely reflecting, is effectively applied to facilitate the recording of good digital holograms captured using a CMOS camera. A green-sensitive photopolymer is used for the study. Digital holograms recorded in successive time intervals of exposure were overlaid and numerically reconstructed. High-contrast stress fringes were generated, and the preliminary results are presented.