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A non-alloy ohmic contact is fabricate on hydrothermally grown n-type ZnO substrate by KrF excimer laser pre- irradiation and metal deposition. The laser irradiation breaks Zn-O bonding, and turns ZnO surface layer to Zn-rich one which has lower sheet resistance than that of bulk, and has n-type conduction. The Zn-rich pre-metallized layer enables current conducting into ZnO substrate with ohmic characteristics. Au/In/ZnOx and In/ZnOx contact fabricated by single pulse laser irradiation has specific contact resistivity of approximately 7 X 10-1 (Omega) cm2. Deterioration of contact resistance is confirmed after 5 minutes annealing at 300 degrees C in N2, which is originated by re-bonding of Zn-O in laser irradiated area.
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Toshimitsu Akane, Koji Sugioka, Katsumi Midorikawa, "KrF-excimer-laser-induced ohmic metallization of ZnO substrate," Proc. SPIE 3933, Laser Applications in Microelectronic and Optoelectronic Manufacturing V, (7 June 2000); https://doi.org/10.1117/12.387558