Paper
11 July 1988 Experimental And Theoretical X-Ray Absorption Near-Edge Study Of III-V Compound Semiconductor Materials
C Schwartz, T L Cole, A K Green, P J Love, Victor Rehn
Author Affiliations +
Proceedings Volume 0911, X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements; (1988) https://doi.org/10.1117/12.945476
Event: 1988 Los Angeles Symposium: O-E/LASE '88, 1988, Los Angeles, CA, United States
Abstract
We report experimental and theoretical near-edge x-ray absorption fine structure (NEXAFS) spectra of clean and arsenic-capped gallium arsenide and the pseudo-binary alloy indium-gallium arsenide. Experimental data were obtained using synchrotron-radiation total-photoelectron-yield spectroscopy from the Ga(M2,3), As(M2,3), In(N2,3), and In(M4,5) edges. In addition, both C(K) and 0(K) NEXAFS spectra, and photon-stimulated ion-desorption mass spectra were obtained to assess and monitor the sample cleanliness. The samples studied were grown by molecular-beam epitaxy at China Lake and capped with arsenic for protection during transit to the Stanford Synchrotron-Radiation Laboratory. We have found by monitoring the As edges that heating the samples to 300 or 350°C completely removes the arsenic cap. Also, we find that after evaporation of the As cap, the NEXAFS spectra are identical for capped and uncapped samples. Theoretical calculations of the arsenic NEXAFS spectra were performed using a full multiple-scattering theory. The inputs to the calculations were ab initio phase shifts, calculated using pseudopotentials and a model geometry. Theoretical calculations of the arsenic NEXAFS spectra of In0.53Ga0.47As crystals are reported also. Here, the calculations are performed by creating many model crystals that have the appropriate stoichiometry and averaging the resulting spectra.
© (1988) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
C Schwartz, T L Cole, A K Green, P J Love, and Victor Rehn "Experimental And Theoretical X-Ray Absorption Near-Edge Study Of III-V Compound Semiconductor Materials", Proc. SPIE 0911, X-Ray and Vacuum Ultraviolet Interaction Data Bases, Calculations, and Measurements, (11 July 1988); https://doi.org/10.1117/12.945476
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KEYWORDS
Arsenic

Chemical species

Gallium arsenide

Absorption

Crystals

Phase shifts

Scattering

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