Down-conversion phosphors based on ions of lanthanides can be used to convert UV/blue components of solar spectrum in near-infrared radiation more suitable for conventional silicon photovoltaic (PV) cells. Comparing to other down convertors, their advantages are long Stokes shift (>300 nm) excluding re-absorption, and environment safety. However, down-conversion efficiency remains an issue. The paper reports on synthesis and characterization of down-conversion phosphor based on lanthanide-doped fluoride NaYF4:Yb3+, Er3+. The phosphor was synthesized using inexpensive wet method and further baked at ~500°C for 1 h to convert NaYF4 matrix from cubic to hexagonal phase. The obtained micro-powder was ball-milled to nano-powder. The phosphor demonstrated down-conversion radiation from 830 to 1100 nm attributed to Yb3+. The Stokes shift was ~600 nm. The intensity of NIR peak radiation increased three times with increasing concentration of Yb3+ from 3 to 14%. A thin-sheet down-convertor of a Luminescent Solar Concentrator (LSC) was made in the form of a projector Mylar transparency coated with nanocolloid of the phosphor in a solution of polymer PMMA in chlorobenzene. Such thin sheet improved by 15% the PV power produced by the LSC being illuminated with a solar simulator as compared to an incandescent light bulb. The obtained results can be used in building more efficient PV green power.
It has been a strong interest in the laser systems with segmented gain/loss with PT-symmetry properties. This paper shows that a fiber laser pumped from one end with a depleting pump meets the conditions of PT-symmetry in the vicinity of the turning point where the gain becomes equal to the loss. The real component of the square of the complex refractive index is symmetric with respect to the turning point while the imaginary part is anti-symmetric. When the gain grows, the laser becomes segmented into two regions with dominating gain or loss. The turning point starts moving towards the other end of the laser. It leads to the appearance, in addition to the laser mode evenly distributed over the entire laser cavity, of a mode that is pushed in the lossy region. The frequency of that mode is in resonance with the length of the lossy region. The experimental data for a 15-m long Erbium doped fiber laser correlated with such hypothesis. We also built a nanocolloid capillary optical amplifier using synthesized phosphor NaY0.83 F4: Yb3+0.14, Er3+0.03. The effect of upconversion emission in such amplifier leads to an additional channel for the pump depletion. This potentially can cause even stronger PT-symmetry effects in a laser based on such optical amplifier.
Nanocolloidal lasers have a potential as inexpensive high-power light sources using non-toxic and non-degradable liquid gain media. However, due to their large core and, as a result, multimode operation they have an issue of strong noise produced by mode competition. An advanced solution would be the selection of active modes down to a single-mode using the parity-time (PT) symmetry approach that originates from the analogy between the Schrödinger wave function equation in quantum mechanics and the wave propagation equation in optics. The PT symmetry lasing will be implemented when spatially inhomogeneous pumping of the nanocolloid generates gain in pumped regions equal in magnitude to the loss in the regions without pumping. When pump energy increases, PT symmetry break occurs and the laser modes split in the active modes amplified in the cavity and those that decay. The goal is to achieve a single-mode nanocolloid laser. On the way to the goal a nanocolloidal capillary optical amplifier was built using highly efficient phosphor NaYF4: Yb3+ , Er3+ emitting at 1550-nm wavelength being pumped with a 980-nm laser diode. The amplifier was configured as a 4-cm long capillary tube made of silica filled with a colloid of 160-nm phosphor nanoparticles in a high- index fluid. Uneven pumping from the side modulated the gain of the amplifier. When the amplifier was to converted into a laser with linear resonator, uneven side pumping produced a variation of the spontaneous emission that could be interpreted as a PT symmetry related mode competition. This potentially could lead to the reduction of active modes and eventually to a single mode operation.
Access to the requested content is limited to institutions that have purchased or subscribe to SPIE eBooks.
You are receiving this notice because your organization may not have SPIE eBooks access.*
*Shibboleth/Open Athens users─please
sign in
to access your institution's subscriptions.
To obtain this item, you may purchase the complete book in print or electronic format on
SPIE.org.
INSTITUTIONAL Select your institution to access the SPIE Digital Library.
PERSONAL Sign in with your SPIE account to access your personal subscriptions or to use specific features such as save to my library, sign up for alerts, save searches, etc.